Optimization of Dye Removal from Textile Wastewater using Activated Carbon from Sawdust

Authors

  • O. A. A. Eletta
  • S. I. Mustapha
  • O. A. Ajayi
  • A. T. Ahmed

Keywords:

Pollution, Wastewater, Textile, Adsorption, ICP-MS, Optimization, Trace metal

Abstract

This study is aimed at developing an adsorbent from sawdust for optimum removal of dye from textile wastewater.  The adsorbent was developed, characterised and, the adsorptive capability for the removal of dye was determined by optimizing the process parameters (adsorbent dosage, contact time and agitation speed) using Response Surface Methodology. The physical and chemical characterization of the effluent was carried out before and after the adsorption studies. From the results, a maximum adsorption capacity of 98.5 % was obtained at the optimized conditions of 1.5 g, 90 min and 275 rpm for adsorbent dose, contact time and agitation speed respectively. The ANOVA of the regression model showed that the model is highly significant with R2 of 0.98. Further analysis carried out revealed that, in addition to dye removal, trace metals were also adsorbed in the process. This fact was established when the concentration of copper in the wastewater was found to decrease from 0.09 ppm to 0.03 ppm corresponding to 66.7 % removal at the end of the process.

References

Adewoye, L. T.; S. I. Mustapha, A. G. Adeniyi, J. O. Tijani, M. A. Amoloye and L. J. Ayinde. (2017). Optimization of nickel (II) and chromium (III) removal from contaminated water using sorghum bicolor. Nigerian Journal of Technology, 36(3): 960-972.
Allègre, C.; P. Moulin, M. Maisseu and F. Charbit. (2006). Treatment and reuse of reactive dyeing effluents. Journal of Membrane Science, 269(1):15-34.
Bhole, B. D.; B. Ganguly, A. Madhuram, D. Deshpande and J. Joshi. (2004). Biosorption of methyl violet, basic fuchsin and their mixture using dead fungal biomass. Current Science, 86(12): 1641-1645.
Garg, V. K.; M. Amita, R. Kumar and R. Gupta. (2004). Basic Dye (Methylene Blue) removal from simulated Wastewater by Adsorption Using Indian Rosewwood Sawdust: a Timber Industry Waste. Dyes and Pigments. 62:243-250.
Grant, J. and Buchanan, I. (2000). Colour Removal from Pulp Mill Effluents Using Immobilized Horseradish Peroxidase. Project Report 2000-8. 1-17
Hettige, A. I. and Mowjood, M. I. M. (2015). Reduction of Colour in Treated Wastewater from Textile Industry Using Sawdusts as Bio-sorbents Tropical Agricultural Research, 26(4): 666-676.
Jin, X., G. and L., Xu, Z. (2007). Decolorization of a dye industry effluent by Aspergillus fumigatus XC6. Appl Microbiol Biotechnol, 74: 239-243.
Kannan, N. and Sundaram, M.M. (2001). Kinetics and Mechanism of Removal of Methylene Blue by Adsorption on Various Carbons – a Comparative Study. Dyes and Pigments 51: 25-40.
Khattri, S. D. and Singh, M. K. (2009). Removal of malachite green from dye wastewater using neem sawdust by adsorption. Journal of Hazardous Materials, 167(1): 1089-1094.
Kyzas, G. Z.; J. Fu and K. A. Matis. (2013). The Change from Past to Future for Adsorbent Materials in Treatment of Dyeing Wastewaters. Materials, 6: 5131-5158.
Malik, R.; D. S. Ramteke and S. R. Wate. (2007). Adsorption of malachite green on groundnut shell waste based powdered activated carbon. Waste Management, 27(9): 1129-1138.
Pang, Y. L. and Abdullah, A. Z. (2013). Current Status of Textile Industry Wastewater Management and Research Progress in Malaysia: A Review. Clean Soil Air Water, 41(8): 751-764.
Pearce, C. I.; J. R. Lloyd and J. T. Guthrie. (2003). The removal of colour from textile wastewater using whole bacterial cells: a review. Dyes and Pigments, 58: 179-196.
Pereira, L. and Alves, M. (2007). Dyes-Environmental Impact and Remediation. Trends Biotechnol., 6: 148-153.
Robinson, T.; G. McMullan, R. Marchant and P. Nigam. (2001). Remediation of dyes in textile e‚uent: a critical review on current treatment technologies with a proposed alternative. Bioresource Technology, 77: 247-255.
Santhy, K. and Selvapathy, P. (2006). Removal of reactive dyes from wastewater by adsorption on coir pith activated carbon. Bioresource Technology, 97(11): 1329-1336.
Sun, Q. and Yang, L. (2003). The adsorption of basic dyes from aqueous solution on modified peat–resin particle. Water Research, 37: 1535-1544.
Suteu, D.; D. Bilba, C. Zaharia and A. Popescu. (2008). Removal of dyes from textile wastewater by sorption onto lignocellulosic materials. Scientific Study and Research, 9(3).
Tan, I. A. W.; A. L. Ahmad and B. H. Hameed. (2008). Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies. Journal of Hazardous Materials, 154(1–3): 337-346.
Tan, I. A. W.; B. H. Hameed and A. L. Ahmad. (2007). Equilibrium and kinetic studies on basic dye adsorption by oil palm fibre activated carbon. Chemical Engineering Journal, 127(1): 111-119.
Wang, X.; X. Gu, D. Lin, F. Dong and X. Wan. (2007). Treatment of acid rose dye conatining wastewater by ozonizing – biological aerated filter. Dyes and Pigments, 74(3): 736-740.

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Published

2018-02-22

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