Comparative Performance Analysis of Bamboo-based (Bambusa vulgaris) Activated Carbon produced through Carbonization and Activation Processes

Authors

  • Christopher Akinbile Federal University of Technology
  • E. M. Epebinu
  • O.O. Olanrewaju
  • A.T. Abolude

Keywords:

Bamboo, Activated Carbon;, FTIR, SEM, Adsorption capacity, Bamboo; Activated Carbon; FTIR; SEM; Adsorption capacity

Abstract

Activated carbon (AC) is one of the numerous cost-effective inputs for treating wastewater in an efficient and cost-effective manner, and several materials have been used to produce AC with diverse results. One such material with a large potential is African Bamboo (Bambusa vulgaris), especially due to its availability. In this study, bamboo was carbonized and then activated using trioxonitrate (V) acid (HNO3) and potassium hydroxide (KOH) as activating agents. The AC was characterized using Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) technologies at 50 μm, 80 μm, 100 μm, and 200 μm magnification. The SEM imagery results at 50 μm and 1500x magnification showed that the AC produced using KOH had the largest and most well-developed pore spaces hence maximum capacity to absorb contaminants compared to HNO3's AC and inactivated carbonated charcoal. The FTIR spectra peak analysis results also confirmed that KOH's AC had the highest number of functional groups on its surface and, therefore, enhanced its adsorption capacity.

References

Ademiluyi, F. T.; S. A. Amadi, and N. J. Amakama (2009). Adsorption and Treatment of Organic Contaminants using Activated Carbon from Waste Nigerian Bamboo. Journal of Applied Science and Environmental Management, 13 (3): 39 – 47.

Akinbile C.O.; A.E. Erazua; B. E. Babalola and F. Ajibade. (2016). Environmental Implications of Animal Wastes Pollution on Agricultural Soil and Water Quality, Soil and Water Research, 11 (3): 172-180.

Awoyale, A.A.; A.C. Eloka-Eboka and A.O. Odubiyi, (2013). Production and Experimental efficiency of activated carbon from local waste bamboo for wastewater treatment. International Journal of Engineering and Applied Sciences. 3 (2): 08 – 17

Chouikhi, N.; J. A. Cecilia; E. Vilarrasa-García; L. Serrano-Cantador; S. Besghaier; M. Chlendi; M. Bagane and R. Castellón, E. (2021). Valorization of agricultural waste as a carbon material for selective separation and storage of CO2, H2 and N2, Biomass and Bioenergy, 155, 106297 -106304 https://doi.org/10.1016/j.biombioe.2021.

Coates, J. (2000). Interpretation of Infrared Spectra, A practical approach. Encyclopedia of Analytical Chemistry. R.A. Meyers (Eds), 10881-10882.

Dutrow, B.L, and Clark, C.M. (2019). Geochemical Instrumentation and Analysis. Assessed from https://serc.carleton.edu/research_education/geochemsheets/techniques/XRD.html on 4th February 2019.

Gerwert, K, and Kotting, C. (2010). Fourier Transform Infrared Spectroscopy (FTIR). In els, (Ed.) 12-18.

Hirunpraditkoon S.; T. Nathaporn; R. R. Anotai and N. Kamchai (2011). Adsorption Capacities of Activated Carbons Prepared from Bamboo by KOH Activation. World Academy of Science, Engineering and Technology International Journal of Chemical, Molecular, Nuclear, Materials, and Metallurgical Engineering 5 (6): 477-481.

Ijaola, O. O.; K. Ogedengbe and A.Y. Sangodoyin (2013). The Efficacy of Activated Carbon Derived from Bamboo in the Adsorption of Water Contaminants. International Journal of Engineering Inventions e-ISSN: 2278-7461, p-ISBN: 2319-6491 2(4): 29-34.

Ilomuanya M. O.; B. Nashiru; N. D. Ifudu and C. I. Igwilo (2017). Effect of pore size and morphology of activated charcoal prepared from midribs of Elaeis guineensis on adsorption of poisons using metronidazole and Escherichia coli O157: H7 as a case study. Journal of Microscopy and Ultrastructure 5 (1): 32-38.

Isa, S.S.M.; M. M. Ramli; N.A.M.A. Hambali; S.R. Kasjoo; M.M. Isa; N.I.M. Nor; N. Khalid and N. Ahmad (2016). Adsorption properties and potential applications of bamboo charcoal: A review. DOI: 10.1051/matecconf/20167801097.

Isa, S.S.M.; M. M. Ramli; D.S.C. Halim; N.A.M. Anhar and N.A.M.A. Hambali (2017). Different carbonization processes of bamboo charcoal using Gigantochloa albociliata. AIP conference proceedings 1885, 020226; DOI: 10.106311.5002420

Jiang, S. (2004). Training Manual of Bamboo Charcoal for Producers and Consumers. Bamboo Engineering Research Center. Nanjing Forestry University.

Joshi S.; M. Adhikari; B. P. Pokharel and R.R. Pradhananga (2013). Effects of Activating Agents on the Activated Carbons Prepared from Lapsi Seed Stone. Research Journal of Chemical Sciences. 3 (5): 19-24.

Khandaker S.; T. Kuba; Y. Toyohara; S. Kamida and Y. Uchikawa (2017). Development of ion-exchange properties of bamboo charcoal modified with concentrated nitric acid. IOP Conf. Series: Earth and Environmental Science 82 (2017) 012002, 3rd International Conference on Water Resource and Environment (WRE 2017).Li, Z.; C. Wang; T. Lei; H. Ma; J. Su; S. Ling and W. Wang (2019). Arched bamboo charcoal as interfacial solar steam generation integrative device with enhanced water purification capacity. Advanced Sustainable Systems, 3 (4): 1800144 - 1800153.

Ma, Z.; Y. Zhang; Y. Shen; J. Wang; Y. Yang; W. Zhang and S. Wang (2019). Oxygen migration characteristics during bamboo torrefaction process based on the properties of torrefied solid, gaseous, and liquid products, Biomass and Bioenergy, 128, 105300 – 105312, https://doi.org/10.1016/j.biombioe.2019.105300.

Masykuri, M. and Purwanto, E. (2019). Batik Industry Wastewater Treatment Using Fito Remediation of Water Hyacinth with Adsorbent consist of Organic Waste Bagasse, Rice Husks and Bamboo Charcoal. in IOP Conference Series: Materials Science and Engineering, 1. 508 (1): 012). IOP Publishing.

Mohan D.; P. K. Singh and K. V. Singh (2007). Wastewater Treatment Using Low-Cost Activated Carbons Derived from Agricultural Byproducts – A case study, Journal of Hazardous Materials. DOI: 10.1016/j.jhazmat.2007.07.079

Moreno-Castilla, C.; F. Carrasco-Marín; M.V. López-Ramón and M.A. Alvarez-Merino (2011) Chemical and physical activation of olive mill wastewater to produce activated carbons, Journal of Hazardous materials, (39):1415-1420

Nam, H.; W. Choi; A. Divine; S.C. Genuino and A. Capareda (2018a). Development of rice straw activated carbon and its utilizations, Journal of Environmental Chemical Engineering, 6 (4): 5221-5229Nam, H.; S. Wang and H.R. Jeong (2018b). TMA and H2S gas removals using metal loaded on rice husk activated carbon for indoor air purification. Fuel, 213, 186-194.

Omiyale, O. (2013). Bamboo and Rattan: vehicle for poverty alleviation in Nigeria. XII world forestry congress, 2003. Quebec City, Canada. 1015-A1

Ren, Q.; Z. Zeng; Z. Jiang and H. Li (2020). Functionalization of renewable bamboo charcoal to improve indoor environment quality in a sustainable way. Journal of Cleaner Production, 246, 119028 -119035.

Topare, N. and Joshi, P. (2016). Characterization of Activated Carbon Prepared from Citrus Sinensis (Orange) Peels by X-Ray Fluorescence Spectroscopy (XRF). Journal of Emerging Trends in Chemical Engineering, 2 (3): 49-51

Wang, Y.; C. Peng; E. Padilla-Ortega; A. Robledo-Cabrera; A. López-Valdivieso, (2020a). Cr (VI) adsorption on activated carbon: Mechanisms, modeling and limitations in water treatment, Journal of Environmental Chemical Engineering, 8, (4): 104031 -104039

Wang, S.; H. Nam; H. Nam (2020b). Preparation of activated carbon from peanut shell with KOH activation and its application for H2S adsorption in confined space Journal of Environmental Chemical Engineering, 8 (2): 103683 -103692

WWAP (United Nations World Water Assessment Programme) (2017). The United Nations World Water Development Report 2017. Wastewater: The Untapped Resource. Paris, Published by United Nations Educational, Scientific and Cultural Organization (UNESCO): pp 16-26

Zhang, X.; X. Mao; L. Pi; T. Wu; Y. Hu (2019). Adsorptive and capacitive properties of the activated carbons derived from pig manure residues, Journal of Environmental Chemical Engineering, 7 (3): 103066 - 103074

Zhou, F. (1998). Bamboo forest cultivation. China Forestry Publishing House. Beijing, China. 105pp

Published

2023-06-27