Effect of Calcination Temperatures on the Chemical, Microstructure, and Strength Characterisation of Borassus Ash-Mortar
DOI:
https://doi.org/10.63746/njtd.v23i2.4645Keywords:
Borassus Ash, Mortar, Microstructure, Compressive Strength, Cement ReplacementAbstract
Studies have shown that biomass ashes from diverse agricultural residues exhibit pozzolanic characteristics, making them suitable for partial cement replacement in mortar production. However, limited studies have explored the feasibility of Borassus ash as a partial replacement of cement in mortar. Information on the material phase changes and microstructure under the varying calcination temperatures is not available in literatures. This study assessed the effect of calcination temperatures on the chemical, microstructure, and strength properties of mortar containing Borassus ash. The Borassus was calcined at four different temperatures: 500, 600, 700, and 800 oC. Mineralogical, chemical, and morphological characterization of the obtained Borassus ashes was conducted. Moreso, the influence of the Borassus ash on the setting time, density, and compressive strength properties of mortar were examined. The results revealed that calcination temperature influences the surface morphology, fineness, porosity, amorphous and crystalline phase of Borassus ash. Borassus ash calcined at a temperature of 600 oC provides a balance between crystalline and amorphous phases, and the highest SiO?, Al?O?, and Fe?O? combination of 82.1%, demonstrating potential to perform better in cement replacement applications, aligning with the ASTM C618 and IS 3812-1 standards requiring a minimum of 70% for pozzolanic materials. A mortar mix containing 15 % Borassus ash as a cement replacement achieved an optimum density and compressive strength of 2218 ± 6 kg/m³ and 14.93 ± 0.2 N/mm2 at 28 days, which were 7.4 and 29.9 % higher than the control mix. The findings demonstrate Borassus ash as a viable alternative to cement in the production of environmentally friendly mortar mixes, providing value for the agro-sourced material.
References
Abdullah, M. M. A. B., Hussin, K., Bnhussain, M., Ismail, K. N., & Ibrahim, W. M. W. (2019). Mechanism and Chemical Reactions of Palm Oil Fuel Ash (POFA) in Calcium Hydroxide Treatment. Construction and Building Materials, 215, 447-455.
Ganesan, K., Rajagopal, K.R., & Thangavel, K. (2008). Rice husk ash blended cement: Assessment of optimal level of replacement for strength and permeability properties of concrete. Construction and Building Materials, 22, 1675-1683.
Jain, M., & Singh, B. (2018). Characterization of Fly Ash for Its Effective Management and Utilization. Journal of Cleaner Production, 172, 1625-1634.
Mansur, A., Adamu, B., & Abdullahi, H. (2021). Effects of hydromethanol hypocotyls extract of Borassus aethiopum on sperm and gonadal indices of male Wistar rats. Journal of Medicinal Plants Research.
Nguyen, T.H. (2010). Contribution à l'étude de la formulation et du procédé de fabrication d'éléments de construction en béton de chanvre.
United Nations. (2012). Earth charter [Online]. Retrieved from official website the United Nations: http://www.un.org/french.
Gabrijel, I., Jel?i? Rukavina, M., & Štirmer, N. (2021). Influence of wood fly ash on concrete properties through filling effect mechanism. Materials, 14(23), 7164. https://doi.org/10.3390/ma14237164
González-Kunz, R. N., Pineda, P., Bras, A., & Morillas, L. (2017). Plant biomass ashes in cement-based building materials: Feasibility as eco-efficient structural mortars and grouts. Sustainable Cities and Society, 31, 151–172. https://doi.org/10.1016/j.scs.2017.03.001
Guo, Z., Chen, Z., Yang, X., Zhang, L., Li, C., He, C., & Xu, W. (2025). The influence of rice husk ash incorporation on the properties of cement-based materials. Materials, 18(2), 460. https://doi.org/10.3390/ma18020460
He, J., Kawasaki, S., & Achal, V. (2020). The utilization of agricultural waste as agro-cement in concrete: A review. Sustainability, 12(17), 6971. https://doi.org/10.3390/su12176971
Ottosen, L. M., Hansen, E. Ø., Jensen, P. E., Kirkelund, G. M., & Golterman, P. (2016). Wood ash used as partly sand and/or cement replacement in mortar. International Journal of Sustainable Development and Planning, 11(5), 781–791. https://doi.org/10.2495/sdp-v11-n5-781-791
Arum, R. C., Arum, C., & Alabi, S. A. (2022). The highs and lows of incorporating pozzolans into concrete and mortar: A review on strength and durability. Nigerian Journal of Technology, 41(2), 197–211. https://doi.org/10.4314/njt.v41i2.1
Ruano Gutiérrez, E., Ferrández, D., Atanes-Sánchez, E., & Ruano de Pablo, M. (2024). Physico-mechanical characterization of masonry mortars for sustainable construction: Experimental study with four different aggregates. Sustainability, 16(14), 6228. https://doi.org/10.3390/su16146228
Singh, A. K., Singh, P., Sharma, P., & Sharma, N. (2023). Environmental effects of cement production: A review. AIP Conference Proceedings, 2721(1), 070009. https://doi.org/10.1063/5.0154039
Firdissa, B., Degefa, S., Mulugeta, E., & Sithole, D. (2025). Optimizing Ethiopian greenhouse gas inventories with customized clinker-specific emission factors in the cement sector. Discover Applied Sciences, 7(1). https://doi.org/10.1007/s42452-025-06608-y
Zhong, W., & Haigh, J. D. (2013). The greenhouse effect and carbon dioxide. Weather, 68(4), 100–105. https://doi.org/10.1002/wea.2072
Dey, A., Pani, A. K., & Acharya, P. K. (2023). Properties of mortar using supplementary cementitious materials. AIP Conference Proceedings, 2740(1), 060015. https://doi.org/10.1063/5.0125840
Fode, T. A., Chande Jande, Y. A., & Kivevele, T. (2023). Effects of different supplementary cementitious materials on durability and mechanical properties of cement composite – Comprehensive review. Heliyon, 9(7), e17924. https://doi.org/10.1016/j.heliyon.2023.e17924
Francioso, V., Lemos-Micolta, E. D., Elgaali, H. H., Moro, C., Rojas-Manzano, M. A., & Velay-Lizancos, M. (2024). Valorization of sugarcane bagasse ash as an alternative SCM: Effect of particle size, temperature-crossover effect mitigation & cost analysis. Sustainability, 16(21), 9370. https://doi.org/10.3390/su16219370
Hansted, F. A. S., Mantegazini, D. Z., Ribeiro, T. M., Gonçalves, C. E. C., & Balestieri, J. A. P. (2022). A mini-review on the use of waste in the production of sustainable Portland cement composites. Waste Management & Research: The Journal for a Sustainable Circular Economy, 41(5), 828–838. https://doi.org/10.1177/0734242x221135246
Sequeira, L., Forero, J., Bravo, M., Evangelista, L., & de Brito, J. (2023). Durability of concrete with partial replacement of Portland cement by incorporating reactive magnesium oxide and fly ash. Materials, 16(7), 2670. https://doi.org/10.3390/ma16072670
Ogbodo, M.C., & Akpabot, A.I. (2021). An assessment of some physical properties of different brands of cement in Nigeria. IOP Conference Series: Materials Science and Engineering, 1048.
Yang, X., Lu, D., Zhu, B., Sun, Z., Li, G., Li, J., Liu, Q.S., & Jiang, G. (2021). Phase transformation of silica particles in coal and biomass combustion processes. Environmental pollution, 118312 .
Magdziarz, A., Gajek, M., Nowak-Wo?ny, D., & Wilk, M. (2017). Mineral phase transformation of biomass ashes – Experimental and thermochemical calculations. Renewable Energy.
Amin, M.N., Hissan, S., Shahzada, K., Khan, K., & Bibi, T. (2019). Pozzolanic Reactivity and the Influence of Rice Husk Ash on Early-Age Autogenous Shrinkage of Concrete. Frontiers in Materials.
Xu, W., Lo, T.Y., Wang, W., Ouyang, D., Wang, P., & Xing, F. (2016). Pozzolanic Reactivity of Silica Fume and Ground Rice Husk Ash as Reactive Silica in a Cementitious System: A Comparative Study. Materials, 9.
Nair, D., Fraaij, A., Klaassen, A., & Kentgens, A.P. (2008). A structural investigation relating to the pozzolanic activity of rice husk ashes. Cement and Concrete Research, 38, 861-869.
Cordeiro, G.C., Filho, R.D., & Fairbairn, E.M. (2008). Use of Ultra-Fine Sugar Cane Bagasse Ash as Mineral Admixture for Concrete. Aci Materials Journal, 105, 487-493.
Tangchirapat, W., & Jaturapitakkul, C. (2010). Strength, drying shrinkage, and water permeability of concrete incorporating ground palm oil fuel ash. Cement & Concrete Composites, 32, 767-774.
Lim, N.H., Ismail, M.A., Lee, H., Hussin, M.W., Sam, A.R., & Samadi, M. (2015). The effects of high volume nano palm oil fuel ash on microstructure properties and hydration temperature of mortar. Construction and Building Materials, 93, 29-34.
Karim, M.R., Hashim, H., & Razak, H.A. (2016). Assessment of pozzolanic activity of palm oil clinker powder. Construction and Building Materials, 127, 335-343.
Balaji, G.R., Vetturayasudharsanan, R., Pavan, P.S., Venkatesh, A., & Pandey, M. (2022). Experimental Investigation on combined effect of eggshell powder and sugarcane bagasse ash as mineral admixture in concrete. IOP Conference Series: Earth and Environmental Science, 1125.
Hari, R., Zhuge, Y., & K.M., M. (2024). Performance assessment of pervious concrete incorporated with calcium silicate hydrates (C-S-H) cultivated on rice husk ash substrates – A trend surface analysis interpretation. Construction and Building Materials.
Prado, R.J., Tiecher, F., Hasparyk, N.P., & Molin, D.D. (2019). Structural characterization of alkali-silica reaction gel: An x-ray absorption fine structure study. Cement and Concrete Research.
Zhang, S., Sun, S., Gao, N., Quan, C., & Wu, C. (2021). Effect of auto thermal biomass gasification on the sintering of simulated ashes. Applications in Energy and Combustion Science.
Namkung, H., Xu, L., Kim, C., Yuan, X., Kang, T.J., & Kim, H. (2016). Effect of mineral components on sintering of ash particles at low temperature fouling conditions. Fuel Processing Technology, 141, 82-92.
Onikeku, O., Shitote, S.M., Mwero, J.N., & Adedeji, A.A. (2019). Evaluation of Characteristics of Concrete Mixed with Bamboo Leaf Ash. The Open Construction & Building Technology Journal.
Aswin, M., Maranatha, E.S., & Nola, L.D. (2021). Effect of use of corn leaf ash on concrete compressive strength. IOP Conference Series: Materials Science and Engineering, 1122.
Khankhaje, E., Jang, H., Kim, J., & Rafieizonooz, M. (2025). Utilizing Rice Husk Ash as Cement Replacement in Pervious Concrete: A Review. Developments in the Built Environment.
Henin, V., & Uglione, P. (2022). Environmental integration tool approach: Self-determined commitment and the adoption of pro-environmental behaviors. Frontiers in psychology, 13, 903103. https://doi.org/10.3389/fpsyg.2022.903103
Morin, J. F., Allan, J., & Jinnah, S. (2024). The survival of the weakest: the echo of the Rio Summit principles in environmental treaties. Environmental Politics, 33(3), 486–507. https://doi.org/10.1080/09644016.2023.2236505
IPCC. (2022). Climate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press. https://www.ipcc.ch/report/ar6/wg3/chapter/chapter-9/
Kumar, S., Roy, S., & Das, P. (2024). Integrating energy efficiency in residential buildings: A user-centric web interface approach. Current World Environment, 19(3), 1223–1234. https://www.cwejournal.org/vol19no3/integrating-energy-efficiency-in-residential-buildings-a-user-centric-web-interface-approach
Li, C., Wang, J., & Liu, Y. (2025). Carbon footprint of the construction sector is projected to double by 2050. Communications Earth & Environment, 6, Article 284. https://www.nature.com/articles/s43247-025-02840-x
Koffi, S., & Konin, A. (2024). Influence of the addition of palm (Borassus aethiopum Mart.) fibers on the durability of compressed earth blocks. Advances in Materials, 13(3), 37–45. https://doi.org/10.11648/j.am.20241303.11
Thomas, B. S., Yang, J., Mo, K. H., Abdalla, J. A., Hawileh, R. A., & Ariyachandra, E. (2021). Biomass ashes from agricultural wastes as supplementary cementitious materials or aggregate replacement in cement/geopolymer concrete: A comprehensive review. Journal of Building Engineering, 40, 102332. https://doi.org/10.1016/j.jobe.2021.102332
Saki, T., Konan, K. H., & Kouassi, K. P. (2020). Nutritional and antinutritional profile of Borassus aethiopum Mart. fruit pulp from Côte d'Ivoire. International Journal of Pharmacy and Pharmaceutical Sciences, 12(11), 35–41.
Mandelot-Matetelot, J. F., Le-Majeur, V., & Mogire, J. (2025). Performance analysis of Ronier fibers (Borassus aethiopum) with silica fume on concrete properties. Engineering, Technology & Applied Science Research, 15(1), 18590–18602. https://doi.org/10.48084/etasr.9591
Villar-Cociña, E., Morales, E.V., Santos, S.F., Savastano, H., & Frías, M. (2011). Pozzolanic behavior of bamboo leaf ash: Characterization and determination of the kinetic parameters. Cement & Concrete Composites, 33, 68-73.
Frías, M., Savastano, H., Villar, E., Sánchez de Rojas, M., & Santos, S.F. (2012). Characterization and properties of blended cement matrices containing activated bamboo leaf wastes. Cement & Concrete Composites, 34, 1019-1023.
Cordeiro, G.C., & Sales, C.P. (2016). Influence of calcining temperature on the pozzolanic characteristics of elephant grass ash. Cement & Concrete Composites, 73, 98-104.
Cordeiro, G.C., & Sales, C.P. (2015). Pozzolanic activity of elephant grass ash and its influence on the mechanical properties of concrete. Cement & Concrete Composites, 55, 331-336.
Kanning, R.C., Portella, K.F., Bragança, M.D., Bonato, M.M., & Santos, J.C. (2014). Banana leaves ashes as pozzolan for concrete and mortar of Portland cement. Construction and Building Materials, 54, 460-465.
Binici, H., Yucegok, F., Aksogan, O., & Kaplan, H. (2008). Effect of Corncob, Wheat Straw, and Plane Leaf Ashes as Mineral Admixtures on Concrete Durability. Journal of Materials in Civil Engineering, 20, 478-483.
Shakouri, M., Exstrom, C.L., Ramanathan, S., & Suraneni, P. (2020). Hydration, strength, and durability of cementitious materials incorporating untreated corn cob ash. Construction and Building Materials, 243, 118171.
Adesanya, D.A., & Raheem, A.A. (2009). A study of the workability and compressive strength characteristics of corn cob ash blended cement concrete. Construction and Building Materials, 23, 311-317.
Roselló, J., Soriano, L., Santamarina, M.P., Akasaki, J.L., Monzó, J.M., & Payá, J. (2017). Rice straw ash: A potential pozzolanic supplementary material for cementing systems. Industrial Crops and Products, 103, 39-50.
Al-Akhras, N., & Abu-Alfoul, B.A. (2002). Effect of wheat straw ash on mechanical properties of autoclaved mortar. Cement and Concrete Research, 32, 859-863.
Biricik, H., Aköz, F., Türker, F., & Berktay, I. (2000). Resistance to magnesium sulfate and sodium sulfate attack of mortars containing wheat straw ash. Cement and Concrete Research, 30, 1189-1197.
Pinheiro, S.M.D.M., Font, A., Soriano, L., Tashima, M. M., Monz´o, J., Borrachero, M. V., & Pay´a, J. (2018) Olive-stone biomass ash (OBA): an alternative alkaline source for the blast furnace slag activation, Construction Building Materials. 178, 327–338.
Pandey, A. & Kumar, B. (2019). Effects of rice straw ash and micro silica on mechanical properties of pavement quality concrete, Journal of Building Engineering. 26, 1–12.
Ikubanni, P., Oki, M., Adeleke, A.A., Adediran, A.A., & Adesina, O.S. (2020). Influence of temperature on the chemical compositions and microstructural changes of ash formed from palm kernel shell. Results in Engineering.
British Standards Institution. (2013). Testing concrete. Methods for mixing and sampling fresh concrete in the laboratory (BS 1881-125:2013). London, UK
British Standards Institution. (2019). Testing hardened concrete. Density of hardened concrete (BS EN 12390-7:2019). London, UK
British Standards Institution. (2019). Testing hardened concrete. Compressive strength of test specimens (BS EN 12390-3:2019). London, UK
ASTM International. (2023). Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete (ASTM C618-23). West Conshohocken, PA
Bureau of Indian Standards. (2013). Pulverized fuel ash – Specification: Part 1 for use as pozzolana in cement, cement mortar and concrete (IS 3812-1:2013). New Delhi, India
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