Production of Reinforced Polyester Composite from Okra Fibre and Sawdust

Authors

  • T. K. Bello Department of Chemical Engineering, Ahmadu Bello University, Samaru Zaria, Kaduna State, Nigeria
  • M. O. Oladipo Department of Chemical Engineering, Ahmadu Bello University, Samaru Zaria, Kaduna State, Nigeria
  • A. Idris Department of Chemical Engineering, Ahmadu Bello University, Samaru Zaria, Kaduna State, Nigeria
  • F. B. Beka Mouka Limited Kaduna, Kakuri Industrial Area Kaduna State, Nigeria.
  • U. P. Unachukwu Department of Chemical Engineering, Ahmadu Bello University, Samaru Zaria, Kaduna State, Nigeria
  • A. Bukar Department of Chemical Engineering, Ahmadu Bello University, Samaru Zaria, Kaduna State, Nigeria

Keywords:

Weight loss, Activation parameters, Adsorption, Optimization, Stainless steel, Castor leaf

Abstract

This research presents properties of okra and sawdust reinforced polyester composite. The compatibility of the simple woven okra and sawdust with polyester was enhanced with stearic acid treatment. FTIR analysis confirmed decrease in hydrophilicity of the fibre and dust. Six composite samples; pure polyester, sawdust reinforced polyester composite, okra reinforced polyester composite, 10% sawdust in okra fibre reinforced composite, 20% sawdust in okra fibre reinforced composite and 30% sawdust in okra fibre reinforced composites were fabricated and characterized. The morphological analysis showed that the homogeneity of polyester in the samples reduces with increase in sawdust filler (10-30 wt%). Water absorption was highest (1.6%) in 30% sawdust in okra. The densities of all the composites were between 3.5 – 4.5 kg/m3. The sawdust reinforced composite recorded low impact energy of 0.25 J while the woven okra fibre reinforced polyester recorded the highest impact energy of 9.9 J. Hardness property reduced as the biomass content increased. Unreinforced polyester recorded the highest average elongation of 25% (1400 µm) and reduced elongation as filler increased. The storage modulus was highest for unreinforced composite at 40 oC but as the temperature reached 81 oC the storage modulus of unreinforced polyester dropped lower than the sawdust composite. The damping factor (1.41) was highest for 20 wt% sawdust/okra polyester composite. This research concludes that sawdust and okra are suitable for lightweight and energy damping materials in automobile applications.

References

Ahmad, F.; H. S. Choi and M. K. Park (2014). A Review: Natural Fiber Composites Selection in View of Mechanical, Light Weight, and Economic Properties. Macromolecular Materials and Engineering, 300 (1): 10-24

Ahmad, M. A. A.; M. S. Abdul Majid, M. J. M. Ridzuan, M. N Mazlee and A. G Gibson. (2018). Dynamic Mechanical Analysis and Effects of Moisture on Mechanical Properties of Interwoven Hemp/Polyethylene Terephthalate (PET) Hybrid Composites. Construction and Building Materials, 179 (3), 265–276.

Asim, M.; M. Jawaid, M. T. Paridah, N. Saba, M. Nasir and R. M. Shahroze. (2019), Dynamic and thermo‐mechanical properties of hybridized kenaf/PALF reinforced phenolic composites. Polym. Compos. 40 (3): 3814-3822.

Asim, M.; M. Jawaid, A. Khan, A. M. Asiri and M. A. Malik. (2020). Effects of Date Palm Fibres loading on Mechanical, and Thermal Properties of Date Palm Reinforced Phenolic Composites. Journal of Materials Research and Technology. 9 (3): 3614-3621

Chaudhary, V.; P. K. Bajpai and S. Maheshwari. (2018). An Investigation on Wear and Dynamic Mechanical behavior of Jute/Hemp/Flax Reinforced Composites and Its Hybrids for Tribological Applications. Fibers Polym, 19 (2): 403–415.

Doddi, P. R. V.; R. Chanamala and S. P. Dora (2019). Dynamic mechanical properties of epoxy based PALF/basalt hybrid composite laminates. Materials Research Express. 6 (1), 245-258.

El Messiry M. (2021) Green Composite as an Adequate Material for Automotive Applications. In: Thomas S. and Balakrishnan P. (eds) Green Composites. Materials Horizons: From Nature to Nanomaterials. Springer, pp 151-208

Gupta, M. K. and Singh, R. (2018). Flexural and Dynamic Mechanical Analysis (DMA) of Polylactic Acid (PLA) Coated Sisal Fibre Reinforced Polyester Composite. Materials Today: Proceedings, 5(2), 6109–6114

Gurunathan, T.; S. Mohanty and S. K. Nayak. (2015). A review of the recent developments in biocomposites based on natural fibres and their application perspectives. Composites Part A: Applied Science and Manufacturing, 77 (1), 1–25.

Hamidon, M. H.; M. T. H Sultan, A. H. Ariffin and A. U. M. Shah. (2019). Effects of fibre treatment on mechanical properties of kenaf fibre reinforced composites: a review. Journal of Materials Research and Technology, 65 (1), 154–.169

Horta, J. F.; F. J. Simões, and A. Mateus. (2017). Study of Wood-Plastic Composites with Reused High Density Polyethylene and Wood Sawdust. Procedia Manufacturing, 12, 221–229. International Conference on Sustainable and Intelligent Manufacturing, (RESIM 2016), 14-17, Leiria, Portugal

Hulle, A.; P. V. Kadole and P. A. Katkar. (2015). Agave Americana Leaf Fibers. Fibres. 3 (1) 64-75.

Ijoyah, M. O. and Dzer, D. M. (2012). Yield Performance of Okra (Abelmoschus esculentus L. Moench) and Maize (Zea mays L.) as Affected by Time of Planting Maize in Makurdi, Nigeria. ISRN Agronomy, 3 (1) 1–7.

Isa, M. T.; U. Shehu, B. O. Aderemi, T. K. Bello, H. I. Audu, U. M. Shittu and A. Y. Atta. (2016). Properties of Chemically Modified Baobab Pod/Sisal Fiber reinforced Low Density Polyethylene Hybrid Composite. Nigerian Journal of Material Science and Engineering. 7(1):130-135.

Krishnasamy, P.; G. Rajamurugan and M. Thirumurugan. (2019). Dynamic mechanical characteristics of jute Fiber and 304 wire mesh reinforced epoxy composite. Journal of Industrial Textiles, 51 (4): 540-558

La Mantia, F. P and Morreale, M. (2011). Green composites: A brief review. Composites Part A: Applied Science and Manufacturing 42 (5): 579–588.

Letebrhan, K.; K. Marie and D. Hewan. (2020). Comparison and optimization for DNA extraction of okra (Abelmoschus esculentus L. Moench). African Journal of Biotechnology, 19(6): 353–361.

Li, M.; Y. Pu, V. M. Thomas, C. G. Yoo, S. Ozcan, Y. Deng and A. J. Ragauskas. (2020). Recent Advancements of Plant-Based Natural Fiber–Reinforced Composites and Their Applications. Composites Part B: Engineering. 200 (1): 1124-1139.

Mandal, S. and Alam, S. (2012). Dynamic mechanical analysis and morphological studies of glass/bamboo fiber reinforced unsaturated polyester resin-based hybrid composites. Journal of Applied Polymer Science, 125(51), E382–E387

Marcovich, N. E.; M. M. Reboredo and M. I. Aranguren, (1996). Composites from sawdust and unsaturated polyester. Journal of Applied Polymer Science, 61(1): 119–124.

Merzoug, A.; B. Bouhamida, Z. Sereir, A. Bezazi, A. Kilic, A and Z. Candan. (2020). Quasi-static and dynamic mechanical thermal performance of date palm/glass fiber hybrid composites. Journal of Industrial Textiles, 49 (7): 2145-2157.

Misganew M.; D. K. N. Rao, K. R. N. Reddy and M. Avvari. (2020). Dynamic Mechanical Properties of Kenaf, Thespesia Lampas and Okra Fiber Polyester Composites. In: Habtu N.; D. Ayele D, S. Fanta, B. Admasu and M. Bitew. (eds) Advances of Science and Technology. ICAST 2019. Lecture Notes of the Institute for Computer Sciences, Social Informatics and Telecommunications Engineering, 308 (2):1457-1469.

Mohammed, L.; M. N. M. Ansari, G. Pua, M. Jawaid and M. S. Islam. (2015). A Review on Natural Fiber Reinforced Polymer Composite and Its Applications. International Journal of Polymer Science, 2015, 1–15.

Nayak, R.; R. Padhye and L. Arnold. (2017). Melt-electrospinning of nanofibers. Electrospun Nanofibers. 7 (3) 11–40.

Negawo, T. A; Y. Polat, F. N. Buyuknalcaci, A. Kilic, N. Saba and M. Jawaid. (2018). Mechanical, Morphological, Structural and Dynamic Mechanical Properties of Alkali Treated Ensete Stem Fibers Reinforced Unsaturated Polyester Composites. Composite Structures. 207, 589-597

Ngbede S.O.; H. N. Ibekwe, S. C. Okpara, U. N. Onyegbule and L. Adejumo. (2017). An Overview of Okra Production, Processing, Marketing, Utilization and Constraints in Ayaragu in Ivo Local Government Area of Ebonyi State, Nigeria. Greener Journal of Agricultural Sciences, 4 (4): 136-143.

Obogai L. E.; Z. Vandi, S. A. Njelle, O. Chukwunwike ans D. I. Obidimma. (2020). Fabrication, Mechanical and Physical Properties of Agba (Prioria Balsamifera) Sawdust Reinforced Polyester composite. International Journal of Applied Science and Engineering review. 3 (1): 7-15.

Odera, R. S.; O. D. Okechukwu, E. M. Ezeh, M. C. Menkitt and P. C Agu. (2021). The exchange of Musa spp. fibre in composite fabrication: a systematic review. Bull Natl Res Cent 45 (1): 1- 8.

Ogunwusi A. A. (2014). Wood Waste Generation in the Forest Industry in Nigeria and Prospects for its Industrial Utilization. Environmental Research, 6 (9): 62-70.

Okonkwo, E. E.; M. O. Ukaegbu and A. P. Eyisi. (2016). A Documentation of Some Traditional Aspects of Wood Consumption in Anaocha, Nigeria. SAGE Open, 6(2): 1-8.

Oluoti K.; G. Megwai, A. Pettersson and T. Richards. (2014). Nigerian wood waste: A dependable and renewable fuel option for power production. World J.Eng.Tech. 2(3): 234-248.

Owoyemi, J. M.; H. O. Zakariya and I. O. Elegbede. (2016). Sustainable wood waste management in Nigeria. Environmental & Socio-Economic Studies, 4(3), 1–9.

Paiva, J. M. F and Frollini E. (2006). Unmodified and Modified Surface Sisal Fibers as Reinforcement of Phenolic and Lignophenolic Matrices Composites: Thermal Analyses of Fibers and Composites. Macromol. Mater. Eng. 291, 405–417.

Poletto, M. (2017). Mechanical, dynamic mechanical and morphological properties of composites based on recycled polystyrene filled with wood flour wastes. Maderas. Ciencia y Tecnología, 19 (4):433-442.

Popelka, A.; S. Zavahir and S. Habib. (2020). ‘Morphology analysis’. In: Al-Maadeed, M.; D. Ponnamma and M. Carignano (eds.) Polymer Science and Innovative Applications, Oxford UK, Elsevier Science, 21–68.

Punyamurthy, R.; D. Sampathkumar, B. Bennehalli, R. P. Ranganagowda, P. V. Badyankal and S. C.

Venkateshappa. (2014). Abaca Fiber Reinforced Hybrid Composites. International Journal of Applied Engineering Research.9 (23): 20273-20286.

Sanjay, M. R.; P. Madhu, M. Jawaid, P. Senthamaraikannan, S. Senthil, and S. Pradeep. (2018). Characterization and properties of natural fibre polymer composites: A comprehensive review. Journal of Cleaner Production, 172, 566–581.

Sethuraman, B.; S. P. Subramani; S. K. Palaniappan, B. Mylsamy and K. Aruchamy. (2020). Experimental investigation on dynamic mechanical and thermal characteristics of Coccinia Indica Fiber reinforced polyester composites. Journal of Engineered Fibers and Fabrics. 15, 1-6

Siakeng, R.; M. Jawaid, H. Ariffin and S. M. Sapuan. (2018). Physical properties of coir and pineapple leaf fibre reinforced polylactic acid hybrid composites. IOP Conference Series: Materials Science and Engineering, 290 (1): 12-31.

Silva-Guzmán, J. A.; R. R. Anda, F. J. Fuentes-Talavera, R. Manríquez-González and M. G. Lomelí-Ramírez. (2018). Properties of Thermoplastic Corn Starch Based Green Composites Reinforced with Barley (Hordeum vulgare L.) Straw Particles Obtained by Thermal Compression. Fibers Polym 19 (9): 1970–1979.

Sujaritjuna, W.; P. Uawongsuwan, W. Pivsa-Arta and H. Hamada. (2013). Mechanical property of surface modified natural fiber reinforced PLA biocomposites 10th Eco-Energy and Materials Science and Engineering (EMSES2012) Energy Procedia 34: 664 – 672

Thitithanasarn, S.; K. Yamada, U. Ishiaku and H Hamada. (2012). The Effect of Curative Concentration on Thermal and Mechanical Properties of Flexible Epoxy Coated Jute Fabric Reinforced Polyamide 6 Composites. Journal of Composite Mater 2 (4):133-145.

Thyavihalli G. Y.; R. S. Mavinkere, J. Parameswaranpillai and S. Siengchin. (2019). Natural Fibres as Sustainable and Renewable Resource for Development of Eco-Friendly Composites: A Comprehensive Review. Frontiers in Materials, 226 (6):1-8

Unterweger, C.; O. Brüggemann and C. Fürst. (2014). Effects of different fibers on the properties of short-fiber-reinforced polypropylene composites, Composites Science and Technology 103: 49-55.

Valadez-Gonzalez, A.; J. M. Cervantes-Uc, R. Olaya and P. J. Herrera-Franco. (1999). Effect of fiber surface treatment on the fiber-matrix bond strength of natural fiber reinforced composites. Compos Part .30 (3): 309-320.

Zhang, Q.; H. Cai, X. Ren, L. Kong, J. Liu and X. Jiang. (2017). The Dynamic Mechanical Analysis of Highly Filled Rice Husk Biochar/High-Density Polyethylene Composites. Polymers, 9(11): 628-639.

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Published

2022-01-20

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