Marine Corrosion Mitigation of Mild Steel in Simulated Sea Water by Leaf Extract of Barteria Fistulosa

Authors

  • K. D. Ogwo Physics Department, College of Basic and Applied Sciences, Rhema University, Aba, Nigeria.
  • L. A. Nnanna Physics Department, Michael Okpara University of Agriculture, Umudike, Nigeria.
  • A. E. Emea Physics Department, Clifford University, Owerrinta, Abia State, Nigeria.
  • U. Joseph Physics Department, Michael Okpara University of Agriculture, Umudike, Nigeria.
  • A. C. Young Physics Department, Gregory University, Uturu, Abia State, Nigeria.

DOI:

https://doi.org/10.63746/njtd.v22i5.3429

Keywords:

isotherm, Bertria fistulosa, efficiency, low carbon steel, corrosion

Abstract

Carbon steel is one of the major materials used in the construction of sea piers as well as oil and gas transit pipes. The corrosion of undersea oil and gas pipelines often lead to leakages which result in financial losses and irreparable damage to marine lives. This study investigated the use of Barteria fistulosa (BF) leaves extract as a non-toxic corrosion inhibitor of low carbon steel in 3.5% NaCl employing weight loss method, potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). The weight loss result indicated a significant drop in metal corrosion upon the introduction of the leaves extract to the salt solution. The correlation coefficient (R2) values obtained from isotherm study showed that Langmuir model best fitted the inhibitor extract adsorption on the metal surface. The values of the Gibb’s free energy of adsorption (?Gads) were negative and ranges between -17 to -9 kJ/mol. This indicates that the adsorption process of the leaves extract is both spontaneous and physical. The weight-loss, PDP and EIS results all showed incremental change in efficiency of the inhibitor as its concentration is raised. This reveals that BF leaves extracts offered a shield to low carbon steel in the simulated sea water environment.

Author Biography

A. C. Young, Physics Department, Gregory University, Uturu, Abia State, Nigeria.

Ahamefula Young

Physics Department, Gregory University, Uturu, Abia State

References

E. Akpan (2022). Environmental consequences of oil spills on marine habitats and the mitigating measures: The Niger Delta Perspective, Journal of Geoscience and Environmental Protection, 10(6), 191-203. doi:10.4236/gep.2022.106012.

A.A. Al-Amiery; R.W. Isahak and W.K. Al-Azzawi (2023). Corrosion inhibitors: Natural and synthetic organic inhibitors. Lubricants, 11(4), 174.

N. Ayawei; N. Augustus and D. Wankasi (2017). Modelling and interpretation of adsorption isotherms. Journal of Chemistry, 1, 3039817 https://doi.org/10.1155/2017/3039817

M. Bouguezzi; J. Scheid; D. Hilhorst; H. Matano; C. Bataillon; F. Lequien and F. Rouillard (2024). Anodic dissolution model with diffusion-migration transport for simulating localized corrosion. Electrochimica Acta, 477, 143806. doi.org/10.1016/j.electacta.2024.143806

F. Cao; J. Wang; Y. Lian; Y. Wang; X. Wang; A. Song and L. Shi (2024). A study on the influence of the electroplating process on the corrosion resistance of zinc-based alloy coatings. Coatings, 13(10), 1774.

H. Casteneda and D.X. Benetton (2008). SRB-biofilm influence in active corrosive sites formed at the steel-electrolyte interface when exposed to artificial seawater conditions. Corrosion Science, 50, 169-1183.

S. Chaudhary and R.K. Tak (2022). Natural Corrosion inhibition and adsorption characteristics of tribulus terrestris plant extract on aluminium in hydrochloric acid environment. Biointerface research in applied chemistry, 12(2), 2603-2617.

A.M. Chidiebere; L. Nnanna; C. Blessing; K. Oguzie; O. Beluonwu; O. Benedict and E. Oguzie (2016). Inhibition of Acid Corrosion of Mild Steel Using Delonix regia Leaves. International letters of chemistry, physics and astronomy, 69, 74-86.

S. Devikala; P. Kamaraj; M. Arthanareeswari and M.B. Patel (2019). Green corrosion inhibition of mild steel by aqueous allium sativum extract in 3.5% NaCl. Material Today Proceeding, 14: 580-589

O.A. Ezzat; S.V. Aigbodion; A.H. Al-lohedan and J.C. Ozoude (2024). Unveiling the corrosion inhibition efficacy and stability of silver nanoparticles synthesized using anacardium occidentale leaf extract for mild steel in a simulated seawater solution. RSC Advances, 14(26), 18395-18405.

M.C. Fatah; A. Diaz and A. Darwin (2019). Corrosion assessment of a leakage pipeline in the seabed: A case study. 4th Annual Applied Science and Engineering Conference. Journal of Physics: Conference series, 1402 066001.

S. Feliu (2020). Electrochemical impedance spectroscopy for the measurement of the corrosion rate of magnesium alloys: Brief review and challenges. Metals, 10(6), 775. https://doi.org/10.3390/met10060775

K. George (2022). Corrosion barrier coatings: Progress and perspectives of the chemical route. Corrosion Material Degradation, 3(3), 376-413.

R. Haldhar; D. Prasad; D. Kamboj; S. Kaya; O. Dagdag and L. Guo (2021). Corrosion inhibition, surface adsorption and computational studies of Momordica charantia extract: A sustainable and green approach. SN Applied Sciences, 3, 25. Doi.org/10.1007/s42452-020-04079-x

Hussein, F. M., Ben, M. S., Taiwo, R., and Tarek, Z. (2023). Analysis and ranking of corrosion causes for water pipelines: A critical review. NPJ Clean Water. doi.org/10.1038/s41545-023-00275-5

G.H. Ibrahim; M. Abdelmotelb; S.M. Elnouby and M.A. Mostafa (2023). Studies on the impact for pyrimidine compounds upon aluminium protection in acidic conditions, both experimentally and theoretically. Egyptian Journal of Chemistry, 66(12), 367 – 378.

A.G. Ingale and A.U. Hivrale (2010). Pharmacological studies of Passiflora and their bioactive compounds. African Journal of Plant Sciences. 4, 417 – 426.

G. Jeanmairet; B. Rotenberg and M. Salanne (2022). Microscopic simulations of electrochemical double-layer capacitors. Chemical Reviews, 122(12), 10860-10898.

S.R. Kachel; B.P. Klein; M.J. Morbec; M. Schöniger; M. Hutter; M. Schmid and G.J. Michael (2020). Chemisorption and Physisorption at the Metal/Organic Interface: Bond Energies of Naphthalene and Azulene on Coinage Metal Surfaces. Journal of Physical Chemistry, 8257 - 8268. https://doi.org/10.1021/acs.jpcc.0c00915

H.G. Kalada; O.K. Orubite and O.A. James (2017). Corrosion inhibition of mild steel in simulated seawater by nymphae pubens leaf extracts. International Journal of Advanced Research in Chemical Science, 4(12), 32-40.

L. Lai; B. Xie; L. Zou; X. Zheng; X. Ma and S. Zhu (2017). Adsorption and corrosion inhibition of mild steel in hydrochloric acid solution by S-allyl-O,O-dialkyldithiophosphates. Results in Physics, 7, 3434-3443.

Y. Li; D. Zhang and J. Wu (2010). Study on kinetics of cathodic reduction of dissolved oxygen in 3.5% sodium chloride solution. Journal of Ocean University of China, 9, 239-243.

M. Liu; J. Zhu; V.A. Popovich; E. Borisov; M.J. Mol and Y. Gonzalez-Garcia (2023). Passive film formation and corrosion resistance of laser-powder bed fusion fabricated NiTi shape memory alloys. Journal of Materials Research and Technology, 23, 2991-3006.

T.J. McGenity; D.B. Folwell; A.B. McKew and G.O. Sanni (2012). Marine Crude oil Biodegradation: A Central role for interspecies interaction. Aquatic Biosystems, 8(10), 1-19

A. Menga; T. Kanstad; D. Cantero; L. Bathen; K. Hornbostel and A. Klausen (2022). Corrosion induced damges and failures of post-tensioned bridges: A literature review. Structural Concrete, 24(1), 84-99. https://doi.org/10.1002/suco.202200297

M. Mobin and S. Zehra (2023). Electrochemical and analytical techniques for sustainable corrosion monitoring: Corrosion control by cathodic protection. Advances, Challenges and Opportunities, 265-279.

A.F. Nunez (2024). Electrochemical analysis of corrosion resistance of manganese-coated annealed steel: Chronoamperometric and voltametric study. Applied Chemistry, 4(4), 367-383.

K.D. Ogwo; L. Nnanna; Y. Ahamefule and E.A. Emea (2024a).

Comparative Investigation of the corrosion protection efficacy of Spondias mombin leaf extracts on AA2024 alloy and low carbon steel in acidic medium. Physical Science International Journal, 28(3), 13-23.

K.D. Ogwo; L. Nnanna; C.A. Young and U. Joseph (2024b). Corrosion mitigation effect of green inhibitor on aluminium alloy (AA2024) in 3.5wt. % NaCl. Proceedings of the maiden research and innovation fair/conference, Michael Okpara University of Agriculture, Umudike, 766-772, Nigeria.

K.D. Ogwo; L. Nnanna; U.C. Onyeije and A.D. Asiegbu (2023). Electrochemical Investigation of the Anti-corrosive Effect of Spondias mombin Leaves Extract on the Corrosion of Aluminium Alloy (AA2024) and Mild Steel in 0.5 M NaCl. Chemical Science International Journal, 32(3), 44-51.

Othman, N. K., Yahya, S., and Ismail, C. M. (2019). Corrosion inhibition of steel in 3.5% NaCl by rice straw extract. Journal of Industrial Engineering & Chemistry, 70, 299-310.

K. Paswan; S. Sharma; P.D. Shashi; M.K. Abdulameer; L. Changhe; Y. Yaser; M. Abbas and E. Tag-Eldin (2023). An analysis of microstructural morphology, surface topography, surface integrity, recast layer, and machining performance of graphene nanosheets on Inconel 718 superalloy: Investigating the impact on EDM characteristics, surface characterizations, and optimization. Journal of Materials Research and Technology, 27, 7138 – 7158.

K.V. Rybalka; L.A. Beketaeva and D.A. Davydov (2021).

Estimation of corrosion rate of AISI 1016 steel by the analysis of polarization curves and using the method of measuring ohmic resistance. Russian Journal of Electrochemistry, 57, 16-21.

R.B. Sheetal; K.A. Singh; M. Singh; T. Sanjeeve; B. Pani and S. Kaya (2023). Advancement of corrosion inhibitor system through N-heterocyclic compounds: a review. Corrosion Engineering Science and Technology, 58(1), 73-101.

K.M. Shwetha; B.M. Praveen and B.K. Devendra (2024). A review on corrosion inhibitors: Types, mechanisms, electrochemical analysis, corrosion rate and efficiency of corrosion inhibitors on mild steel in an acidic environment. Results in Surfaces and Interfaces, 16, 100258. doi.org/10.1016/j.rsurfi.2024.100258

R. Solmaz; A. Salci; Y.A. Dursun and G. Kardas (2023). A comprehensive study on the adsorption, corrosion inhibition efficiency and stability of acriflavine on mild steel in 1 M HCl solution. Colloids and Surfaces: A Physicochemical and Engineering Aspects, 674, 131908. Doi.org/10.1016/j.colsurfa.2023.131908

C. Song; Y. Li; F. Wu; J. Luo; L. Li and G. Li (2023). Failure analysis of the crack and leakage of a crude oil pipeline under CO2-Steam flooding. Processes, 11(5), 1567.

Y. Zhai; X. Guo; Y. He and Z. Li (2023). Corrosion resistance and mechanical properties of electrodeposited Co-W/ZrO2 composite coatings. International Journal of Electrochemical Science, 18(3), 100015. https//doi.org/10.1016/j.ijoes.2023.01.015

A. Zakeri; E. Bahmani and A.S. Aghdam (2022). Plant extracts as sustainable and green corrosion inhibitors for protection of ferrous metals in corrosive media. A mini review. Corrosion Communications, 5, 25-38.

Published

2025-12-31

Similar Articles

<< < 4 5 6 7 8 9 10 11 12 13 14 15 > >> 

You may also start an advanced similarity search for this article.